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77-100 nucleophilic; aromatic; 167-177 radical, 323-335 Sulphenyl compounds, 320 Sulphonation, 29, 140, 164 Sulphonium salts, 95, 99 cyclic, 95 elimination from, 258 Sulphur trioxide, in sulphonation, 140 Sulphuryl chloride, in chlorination, 327 Super acids, 102, 129, 181 Suprafacial shifts, 353 Symmetry controlled reactions, 340-357 activationparameters, 342 'allowed', 348 antarafacial shifts, 353 Claisen rearrangement, 355 concerted v.
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